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material, used, processing, components, dimensions, composition, product, industry

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Geym

Feb. 04, 2024
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Fiberglass

Background

Fiberglass refers to a group of products made from individual glass fibers combined into a variety of forms. Glass fibers can be divided into two major groups according to their geometry: continuous fibers used in yarns and textiles, and the discontinuous (short) fibers used as batts, blankets, or boards for insulation and filtration. Fiberglass can be formed into yarn much like wool or cotton, and woven into fabric which is sometimes used for draperies. Fiberglass textiles are commonly used as a reinforcement material for molded and laminated plastics. Fiberglass wool, a thick, fluffy material made from discontinuous fibers, is used for thermal insulation and sound absorption. It is commonly found in ship and submarine bulkheads and hulls; automobile engine compartments and body panel liners; in furnaces and air conditioning units; acoustical wall and ceiling panels; and architectural partitions. Fiberglass can be tailored for specific applications such as Type E (electrical), used as electrical insulation tape, textiles and reinforcement; Type C (chemical), which has superior acid resistance, and Type T, for thermal insulation.

Though commercial use of glass fiber is relatively recent, artisans created glass strands for decorating goblets and vases during the Renaissance. A French physicist, Rene-Antoine Ferchault de Reaumur, produced textiles decorated with fine glass strands in 1713, and British inventors duplicated the feat in 1822. A British silk weaver made a glass fabric in 1842, and another inventor, Edward Libbey, exhibited a dress woven of glass at the 1893 Columbian Exposition in Chicago.

Glass wool, a fluffy mass of discontinuous fiber in random lengths, was first produced in Europe at the turn of the century, using a process that involved drawing fibers from rods horizontally to a revolving drum. Several decades later, a spinning process was developed and patented. Glass fiber insulating material was manufactured in Germany during World War I. Research and development aimed at the industrial production of glass fibers progressed in the United States in the 1930s, under the direction of two major companies, the Owens-Illinois Glass Company and Corning Glass Works. These companies developed a fine, pliable, low-cost glass fiber by drawing molten glass through very fine orifices. In 1938, these two companies merged to form Owens-Corning Fiberglas Corp. Now simply known as Owens-Corning, it has become a $3-billion-a-year company, and is a leader in the fiberglass market.

Raw Materials

The basic raw materials for fiberglass products are a variety of natural minerals and manufactured chemicals. The major ingredients are silica sand, limestone, and soda ash. Other ingredients may include calcined alumina, borax, feldspar, nepheline syenite, magnesite, and kaolin clay, among others. Silica sand is used as the glass former, and soda ash and limestone help primarily to lower the melting temperature. Other ingredients are used to improve certain properties, such as borax for chemical resistance. Waste glass, also called cullet, is also used as a raw material. The raw materials must be carefully weighed in exact quantities and thoroughly mixed together (called batching) before being melted into glass.

The Manufacturing
Process

Melting

  • 1 Once the batch is prepared, it is fed into a furnace for melting. The furnace may be heated by electricity, fossil fuel, or a combination of the two. Temperature must be precisely controlled to maintain a smooth, steady flow of glass. The molten glass must be kept at a higher temperature (about 2500°F [1371°C]) than other types of glass in order to be formed into fiber. Once the glass becomes molten, it is transferred to the forming equipment via a channel (forehearth) located at the end of the furnace.

Forming into fibers

  • 2 Several different processes are used to form fibers, depending on the type of fiber. Textile fibers may be formed from molten glass directly from the furnace, or the molten glass may be fed first to a machine

Continuous-filament process

  • 3 A long, continuous fiber can be produced through the continuous-filament process. After the glass flows through the holes in the bushing, multiple strands are caught up on a high-speed winder. The winder revolves at about 2 miles (3 km) a minute, much faster than the rate of flow from the bushings. The tension pulls out the filaments while still molten, forming strands a fraction of the diameter of the openings in the bushing. A chemical binder is applied, which helps keep the fiber from breaking during later processing. The filament is then wound onto tubes. It can now be twisted and plied into yarn.

Staple-fiber process

  • 4 An alternative method is the staplefiber process. As the molten glass flows through the bushings, jets of air rapidly cool the filaments. The turbulent bursts of air also break the filaments into lengths of 8-15 inches (20-38 cm). These filaments fall through a spray of lubricant onto a revolving drum, where they form a thin web. The web is drawn from the drum and pulled into a continuous strand of loosely assembled fibers. This strand can be processed into yarn by the same processes used for wool and cotton.

Chopped fiber

  • 5 Instead of being formed into yarn, the continuous or long-staple strand may be chopped into short lengths. The strand is mounted on a set of bobbins, called a creel, and pulled through a machine which chops it into short pieces. The chopped fiber is formed into mats to which a binder is added. After curing in an oven, the mat is rolled up. Various weights and thicknesses give products for shingles, built-up roofing, or decorative mats.

Glass wool

  • 6 The rotary or spinner process is used to make glass wool. In this process, molten glass from the furnace flows into a cylindrical container having small holes. As the container spins rapidly, horizontal streams of glass flow out of the holes. The molten glass streams are converted into fibers by a downward blast of air, hot gas, or both. The fibers fall onto a conveyor belt, where they interlace with each other in a fleecy mass. This can be used for insulation, or the wool can be sprayed with a binder, compressed into the desired thickness, and cured in an oven. The heat sets the binder, and the resulting product may be a rigid or semi-rigid board, or a flexible batt.

Protective coatings

  • 7 In addition to binders, other coatings are required for fiberglass products. Lubricants are used to reduce fiber abrasion and are either directly sprayed on the fiber or added into the binder. An anti-static composition is also sometimes sprayed onto the surface of fiberglass insulation mats during the cooling step. Cooling air drawn through the mat causes the anti-static agent to penetrate the entire thickness of the mat. The anti-static agent consists of two ingredients—a material that minimizes the generation of static electricity, and a material that serves as a corrosion inhibitor and stabilizer.

    Sizing is any coating applied to textile fibers in the forming operation, and may contain one or more components (lubricants, binders, or coupling agents). Coupling agents are used on strands that will be used for reinforcing plastics, to strengthen the bond to the reinforced material.

    Sometimes a finishing operation is required to remove these coatings, or to add another coating. For plastic reinforcements, sizings may be removed with heat or chemicals and a coupling agent applied. For decorative applications, fabrics must be heat treated to remove sizings and to set the weave. Dye base coatings are then applied before dying or printing.

Forming into shapes

  • 8 Fiberglass products come in a wide variety of shapes, made using several processes. For example, fiberglass pipe insulation is wound onto rod-like forms called mandrels directly from the forming units, prior to curing. The mold forms, in lengths of 3 feet (91 cm) or less, are then cured in an oven. The cured lengths are then de-molded lengthwise, and sawn into specified dimensions. Facings are applied if required, and the product is packaged for shipment.

Quality Control

During the production of fiberglass insulation, material is sampled at a number of locations in the process to maintain quality. These locations include: the mixed batch being fed to the electric melter; molten glass from the bushing which feeds the fiberizer; glass fiber coming out of the fiberizer machine; and final cured product emerging from the end of the production line. The bulk glass and fiber samples are analyzed for chemical composition and the presence of flaws using sophisticated chemical analyzers and microscopes. Particle size distribution of the batch material is obtained by passing the material through a number of different sized sieves. The final product is measured for thickness after packaging according to specifications. A change in thickness indicates that glass quality is below the standard.

Fiberglass insulation manufacturers also use a variety of standardized test procedures to measure, adjust, and optimize product acoustical resistance, sound absorption, and sound barrier performance. The acoustical properties can be controlled by adjusting such production variables as fiber diameter, bulk density, thickness, and binder content. A similar approach is used to control thermal properties.

The Future

The fiberglass industry faces some major challenges over the rest of the 1990s and beyond. The number of producers of fiberglass insulation has increased due to American subsidiaries of foreign companies and improvements in productivity by U.S. manufacturers. This has resulted in excess capacity, which the current and perhaps future market cannot accommodate.

In addition to excess capacity, other insulation materials will compete. Rock wool has become widely used because of recent process and product improvements. Foam insulation is another alternative to fiberglass in residential walls and commercial roofs. Another competing material is cellulose, which is used in attic insulation.

Because of the low demand for insulation due to a soft housing market, consumers are demanding lower prices. This demand is also a result of the continued trend in consolidation of retailers and contractors. In response, the fiberglass insulation industry will have to continue to cut costs in two major areas: energy and environment. More efficient furnaces will have to be used that do not rely on only one source of energy.

With landfills reaching maximum capacity, fiberglass manufacturers will have to achieve nearly zero output on solid waste without increasing costs. This will require improving manufacturing processes to reduce waste (for liquid and gas waste as well) and reusing waste wherever possible.

Such waste may require reprocessing and remelting before reusing as a raw material. Several manufacturers are already addressing these issues.

Where To Learn More

Books

Aubourg, P.F., C. Crall, J. Hadley, R.D. Kaverman, and D.M. Miller. "Glass Fibers, Ceramics and Glasses," in Engineered Materials Handbook, Vol. 4. ASM International, 1991, pp. 1027-31.

McLellan, G.W. and E.B. Shand. Glass Engineering Handbook. McGraw-Hill, 1984.

Pfaender, H.G. Schott Guide To Glass. Van Nostrand Reinhold Company, 1983.

Tooley, F.V. "Fiberglass, Ceramics and Glasses," in Engineered Materials Handbook, Vol. 4. ASM International, 1991, pp. 402-08.

Periodicals

Hnat, J.G. "Recycling of Insulation Fiberglass Waste." Glass Production Technology International, Sterling Publications Ltd., pp. 81-84.

Webb, R.O. "Major Forces Impacting the Fiberglass Insulation Industry in the 1990s." Ceramic Engineering and Science Proceedings, 1991, pp. 426-31.

Laurel M. Sheppard

Fiberglass has become a ubiquitous product in today’s world. You almost certainly have several fiberglass products in your home (or even on it). In 2020, total global glass fiber demand totaled 10.7 billion pounds. And yet, just 100 years ago, total demand was about zero. 

So how did we get here? This post tells the fascinating story of the creation of fiberglass and how it became one of the most important industrial products. 

Before diving in, we should start by clarifying our terms. “Fiberglass” is actually used to refer to two distinct things. Sometimes, the term is referring to glass fibers, which can be found, for instance, in insulation. On the other hand, the term is also used to refer to the combination of glass fibers and a polymer matrix, like the fiberglass hull of a speed boat. A more accurate term for the latter is “FRP,” or “Fiber Reinforced Polymer.” We’ll use that term in what follows to avoid confusion.

Early Experiments with Glass Fibers

If you’ve ever had the chance to see a glassblower at work, perhaps you’ve seen molten glass being drawn out into surprisingly fine strands. There’s nothing particularly challenging about that. We know the ancient Egyptians, Phoenicians, and Greeks understood how to make delicate glass threads and would use them for decorative purposes.

But making some strands by hand and producing a large number of very fine glass fibers are two different things. In the 1800s, people in various places began to experiment with techniques for achieving this much harder result. The first patent in the US for the production of glass fiber was issued to Hermann Hammesfahr in 1880. He developed a cloth woven from glass fibers and silk.

His patent was purchased by Libbey Glass of Toledo, OH, which produced lampshades and a dress made from the cloth to be displayed at the 1893 World’s Fair in Chicago. The dress received a lot of attention, though commercial applications would have to wait for further developments.

A Key Breakthrough

Those developments came in 1932. The depression was being felt acutely by glassmaker Owens-Illinois, in Toledo, OH, as the economic downturn had lowered demand for glass bottles. Games Slayter, an engineer at the company, was working on ways to produce glass fibers as a strategy for finding new markets for glass. 

Another employee at Owens-Illinois, Dale Kleist, was experimenting with fusing glass blocks together using molten glass sprayed out of a gun originally designed for spraying molten bronze. When he attempted to spray the glass, however, the gun emitted instead a shower of fine glass strands. Slayter immediately saw the potential of this accidental discovery and honed the process of producing large quantities of glass fiber efficiently and cheaply, which was patented in 1933. 

The first product Slayter made with these new glass fibers was an air filter, which went on the market in 1932. This was to be the first commercially successful product made of glass fiber.

At the same time, Corning Glass of New York was also working on methods of producing glass fibers. The company approached Owens-Illinois to collaborate on research. In 1938 these companies formed the Owens-Corning Fiberglas Company (their name for the product had only one ‘s’), which continued to perfect techniques of industrial glass fiber production.

The Creation of FRP

Very soon after the discovery of methods to produce glass fiber in commercial quantities, engineers realized the potential to use it as a reinforcing material in a composite. The idea itself wasn’t new. Chemist Leo Baekeland, who invented the first synthetic plastic Bakelite in 1907, used asbestos fibers to reinforce the product.

During WWII, glass fibers were embedded in various resins to create the first examples of FRP using fiberglass. The early examples were used exclusively in military applications, particularly for aircraft parts. 

An important breakthrough came in the development of a polyester resin called Laminac, produced by American Cyanamid in 1943. Whereas previous polymers had to be cured with high heat, this polymer could be used and cured (using a hardener additive) at room temperature. This allowed for much greater flexibility in the fabrication of FRP.

Soon after the availability of this resin, the first FRP boat was built in Toledo by Ray Greene. In 1945, an FRP car prototype, called the Scarab, was built and driven across the country. In the 1950s, FRP using glass fibers gradually expanded into the range of products we associate with it today.

Fiberglass Today

The process for manufacturing fiberglass has changed a bit since the innovations of Kleist and Slayter. Their method of subjecting a stream of molten glass to pressurized air or steam is still in use, though in an updated form. The more common method of production involves forcing molten glass through tiny nozzles to create fine strands of glass, which are then drawn into a spool.

Different kinds of glass fibers are produced, depending upon the application for the finished product. The kind of glass fibers used in insulation, for example, are created in such a way as to trap lots of pockets of air in the glass. This has obvious advantages for a product used to insulate. Some types of class are created to have a higher tensile strength, while others are formulated to be especially resistant to certain chemicals or environmental conditions.

The most common applications of fiberglass are in the building industry. Most new houses are insulated using fiberglass batting and standard asphalt shingles also contain fiberglass reinforcement. 

In addition, fiberglass combined with resins is used in numerous applications where a strong, lightweight, and highly durable material is called for. This includes components in the auto and aviation industry, boat construction, sporting goods, storage tanks, shower stalls, and numerous other examples. 

FRP use in construction and industry continues to expand because of the useful properties of this versatile composite. At Tencom, we have seen this growth first hand as we have continually developed our expertise and capacity in the production of pultruded fiberglass products. If you’d like to hear more about what fiberglass can do for you, please get in touch.

material, used, processing, components, dimensions, composition, product, industry

The History of Fiberglass

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